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Dichloromethane-d2
99.8 atom%D
| Item number | 1076-10X0.75ML |
| CAS | 1665-00-5 |
| Formula | CCl2D2 |
| Molecular weight | 86,94 g/mol |
| Quantity | 10X0.75ML |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
99.5 atom%D |  | 1075-10X0.75ML | 10X1ML | Please log in. |
99.5 atom%D |  | 1075-1X10ML | 1X10ML | Please log in. |
99.5 atom%D |  | 1075-1X25ML | 1X25ML | Please log in. |
99.5 atom%D |  | 1075-1X50ML | 1X50ML | Please log in. |
99.5 atom%D |  | 1075-1X5ML | 1X5ML | Please log in. |
99.8 atom%D |  | 1076-10X0.75ML | 10X1ML | Please log in. |
99.8 atom%D |  | 1076-1X100ML | 1X100ML | Please log in. |
99.8 atom%D |  | 1076-1X10ML | 1X10ML | Please log in. |
99.8 atom%D |  | 1076-1X25ML | 1X25ML | Please log in. |
99.8 atom%D |  | 1076-1X50ML | 1X50ML | Please log in. |
99.9 atom%D |  | 1077-10X0.75ML | 10X1ML | Please log in. |
100 atom%D |  | 1078-10X0.75ML | 10X1ML | Please log in. |
100 atom%D |  | 1078-1X10ML | 1X10ML | Please log in. |
Dichloromethane-d2, cont. 0,03 v/v% TMS 99.5 atom%D |  | 1270-10X0.75ML | 10X1ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 15.10.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Dichloromethane-d2 |
| Catalog No.: | 1076-10X0.75ML |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Permoserstrasse 15 04318 Leipzig Germany Tel. +49 341 5295 183 Fax. +49 341 5295 182 E-mail: info@armar-europa.de |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 2), H351 Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Specific target organ toxicity - repeated exposure, Oral (Category 2), Liver, Blood, H373 Specific target organ toxicity - repeated exposure, Inhalation (Category 2), Central nervous system, H373 |
| Label elements | |
| Pictogram | GHS07 exclam exclam GHS08 silhouete silhouete |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Warning Hazard statement(s) H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H373 May cause damage to organs (Liver, Blood) through prolonged or repeated exposure if swallowed. H373 May cause damage to organs (Central nervous system) through prolonged or repeated exposure if inhaled. Precautionary statement(s) P261 Avoid breathing vapours. P281 Use personal protective equipment as required. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : dichloro(2H2)methane Formula : CD2Cl2 Molecular weight : 86,95 g/mol CAS-No. : 1665-00-5 EC-No. : 216-776-0 Component Classification Concentration DICHLOROMETHANE-D2 Skin Irrit. 2; Eye Irrit. 2; Carc. 2; STOT SE 3; H315, H319, H351, H336 <= 100 % |
| Formula | CCl2D2 |
| Molecular Weight (g/mol) | 86.94 |
| CAS-No. | 1665-00-5 |
| FIRST AID MEASURES | 4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13 |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Heat sensitive. Store under inert gas. Hygroscopic. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -96,99 °C f) Initial boiling point and boiling range 40 °C - lit. g) Flash point No data available h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 22 %(V) Lower explosion limit: 14 %(V) k) Vapour pressure 1.687,3 hPa at 55 °C 470,8 hPa at 20 °C l) Vapour density 3 - (Air = 1.0) m) Relative density 1,362 g/cm3 at 25 °C n) Water solubility slightly soluble o) Partition coefficient: n-octanol/water No data available p) Auto-ignition temperature 556,1 °C 662,0 °C q) Decomposition No data available temperature r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapour density 3 - (Air = 1.0) |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat 10.5 Incompatible materials Alkali metals, Aluminum, Strong oxidizing agents, Bases 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas Other decomposition products - No data available In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LDLo Oral - Human - 357 mg/kg Remarks: (RTECS) LD50 Oral - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - 4 h - 60,14 mg/l Remarks: (Lit.) LD50 Dermal - Rat - male and female - > 2.000 mg/kg (OECD Test Guideline 402) Skin corrosion/irritation Skin - Rabbit Result: Irritations - 4 h (OECD Test Guideline 404) Repeated or prolonged exposure may cause skin irritation and dermatitis, due to degreasing properties of the product. Serious eye damage/eye irritation Eyes - Rabbit Result: Eye irritation Remarks: (ECHA) Respiratory or skin sensitisation Local lymph node assay (LLNA) - Mouse Result: negative (OECD Test Guideline 429) Germ cell mutagenicity Ames test Salmonella typhimurium Result: positive Mutagenicity (mammal cell test): chromosome aberration. Chinese hamster ovary cells Result: positive OECD Test Guideline 474 Mouse - male and female - Bone marrow Result: negative Carcinogenicity Suspected of causing cancer. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Inhalation - May cause drowsiness or dizziness. - Central nervous system Acute oral toxicity - Nausea, Vomiting, Risk of aspiration upon vomiting., Aspiration may cause pulmonary oedema and pneumonitis. Acute inhalation toxicity - mucosal irritations Specific target organ toxicity - repeated exposure Aspiration hazard Additional Information Repeated dose toxicity - Rat - male and female - Oral - 104 Weeks - No observed adverse effect level - 6 mg/kg Repeated dose toxicity - Rat - male and female - Inhalation - 104 Weeks RTECS: Not available Dichloromethane is metabolized in the body producing carbon monoxide which increases and sustains carboxyhemoglobin levels in the blood, reducing the oxygen-carrying capacity of the blood., Acts as a simple asphyxiant by displacing air., anesthetic effects, Difficulty in breathing, Headache, Dizziness, Prolonged or repeated contact with skin may cause:, defatting, Dermatitis, Contact with eyes can cause:, Redness, Blurred vision, Provokes tears., Effects due to ingestion may include:, Gastrointestinal discomfort, Central nervous system depression, Paresthesia., Drowsiness, Convulsions, Conjunctivitis., Pulmonary edema. Effects may be delayed., Irregular breathing., Stomach/intestinal disorders, Nausea, Vomiting, Increased liver enzymes., Weakness, Heavy or prolonged skin exposure may result in the absorption of harmful amounts of material., Abdominal pain, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: After absorption of large quantities: CNS disorders, Drowsiness, Dizziness, drop in blood pressure, Cardiac irregularities, depressed respiration, inebriation, Unconsciousness, narcosis, respiratory paralysis Swallowing may result in damage to the following: Liver, Kidney The following applies to aliphatic halogenated hydrocarbons in general: systemic effect: narcosis, cardiovascular disorders. Toxic effect on liver, kidneys. Other dangerous properties can not be excluded. This substance should be handled with particular care. Blood - Irregularities - Based on Human Evidence |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish flow-through test LC50 - Pimephales promelas (fathead minnow) - 193 mg/l - 96 h (US-EPA) Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 27 mg/l - 48 h (US-EPA) Toxicity to algae static test EbC50 - Pseudokirchneriella subcapitata (green algae) - > 662 mg/l - 96 h (OECD Test Guideline 201) Toxicity to bacteria static test EC50 - activated sludge - 2.590 mg/l - 40 min (OECD Test Guideline 209) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 68 % - Readily biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Discharge into the environment must be avoided |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1593 IMDG: 1593 IATA: 1593 14.2 UN proper shipping name ADR/RID: DICHLOROMETHANE IMDG: DICHLOROMETHANE IATA: Dichloromethane 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |