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1,4-Dibromobenzene-d4

99 atom%D

Item number1071-1X5G
CAS4165-56-4
FormulaC6Br2D4
Molecular weight239,93 g/mol
Quantity 1X5G
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1,4-Dibromobenzene-d4

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    1,4-Dibromobenzene-d4

    99 atom%D

    1071-1X1G
    4165-56-4

    1X1G

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    1,4-Dibromobenzene-d4

    99 atom%D

    1071-1X5G
    4165-56-4

    1X5G

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    Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
    Classifications according to Regulation (EC) No 1272/2008.
    Printdate 27.07.2024
    IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
    Product name:1,4-Dibromobenzene-d4
    Catalog No.:1071-1X5G
    Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
    uses: R&D
    Uses advised against:HPC Standards GmbH
    Permoserstrasse 15

    04318 Leipzig
    Germany

    Tel. +49 341 5295 183
    Fax. +49 341 5295 182
    E-mail: info@armar-europa.de
    HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
    Classification according to Regulation (EC) No 1272/2008
    Skin irritation (Category 2), H315
    Eye irritation (Category 2), H319
    Specific target organ toxicity - single exposure (Category 3), H335
    Short-term (acute) aquatic hazard (Category 1), H400
    Label elements
    PictogramGHS07 exclam
    exclam
    GHS09 Aquatic-pollut-red
    Aquatic-pollut-red
    2.2 Label elements
    Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Warning
    Hazard statement(s)
    H315 Causes skin irritation.
    H319 Causes serious eye irritation.
    H335 May cause respiratory irritation.
    H400 Very toxic to aquatic life.
    Precautionary statement(s)
    P261 Avoid breathing dust.
    P273 Avoid release to the environment.
    P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
    Remove contact lenses, if present and easy to do. Continue
    rinsing.
    Supplemental Hazard
    Statements
    none
    2.3 Other hazards - none
    COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
    Formula : C6D4Br2
    Molecular weight : 239,85 g/mol
    CAS-No. : 4165-56-4
    Component Classification Concentration
    1,4-Dibromobenzene-d4
    Skin Irrit. 2; Eye Irrit. 2;
    STOT SE 3; Aquatic Acute
    1; H315, H319, H335,
    H400
    M-Factor - Aquatic Acute:
    1
    <= 100 %
    FormulaC6Br2D4
    Molecular Weight (g/mol)239.93
    CAS-No.4165-56-4
    FIRST AID MEASURES4.1 Description of first-aid measures
    General advice
    Consult a physician. Show this material safety data sheet to the doctor in attendance.
    If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration.
    Consult a physician.
    In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
    In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult
    a physician.
    4.2 Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section
    2.2) and/or in section 11
    4.3 Indication of any immediate medical attention and special treatment needed
    No data available
    FIRE-FIGHTING MEASURES5.1 Extinguishing media
    Suitable extinguishing media
    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
    5.2 Special hazards arising from the substance or mixture
    Carbon oxides, Hydrogen bromide gas
    5.3 Advice for firefighters
    Wear self-contained breathing apparatus for firefighting if necessary.
    5.4 Further information
    No data available
    ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or
    gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.
    For personal protection see section 8.
    6.2 Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
    Discharge into the environment must be avoided.
    6.3 Methods and materials for containment and cleaning up
    Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in
    suitable, closed containers for disposal.
    6.4 Reference to other sections
    For disposal see section 13
    HANDLING AND STORAGE7.1 Precautions for safe handling
    Avoid contact with skin and eyes. Avoid formation of dust and aerosols.
    Provide appropriate exhaust ventilation at places where dust is formed.
    For precautions see section 2.2.
    7.2 Conditions for safe storage, including any incompatibilities
    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
    Store under inert gas. hygroscopic
    7.3 Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
    EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment

    Eye/face protection Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
    Body Protection Impervious clothing, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
    PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
    a) Appearance Form: solid
    b) Odor No data available
    c) Odor Threshold No data available
    d) pH No data available
    e) Melting
    point/freezing point
    Melting point/range: 88 - 90 °C - lit.
    f) Initial boiling point 219 °C and boiling range
    g) Flash point 100,00 °C - closed cup
    h) Evaporation rate No data available
    i) Flammability (solid,
    gas)
    No data available
    j) Upper/lower
    flammability or
    explosive limits
    No data available
    k) Vapor pressure No data available
    l) Vapor density No data available
    m) Relative density 1,872 g/mL at 25 °C1,872 g/cm3 at 25 °C
    n) Water solubility No data available
    o) Partition coefficient:
    n-octanol/water
    No data available
    p) Autoignition
    temperature
    No data available
    q) Decomposition
    temperature
    No data available
    r) Viscosity No data available
    s) Explosive properties No data available
    t) Oxidizing properties No data available
    9.2 Other safety information
    No data available
    STABILITY AND REACTIVITY10.1 Reactivity
    No data available
    10.2 Chemical stability
    Stable under recommended storage conditions.
    10.3 Possibility of hazardous reactions
    No data available
    10.4 Conditions to avoid
    No data available
    10.5 Incompatible materials
    Strong oxidizing agents
    10.6 Hazardous decomposition products
    No data available
    Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen
    bromide gas
    In the event of fire: see section 5
    TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
    Acute toxicity
    LD50 Oral - Mouse - 3.120 mg/kg
    Inhalation: Irritating to respiratory system.
    Skin corrosion/irritation
    No data available
    Serious eye damage/eye irritation
    No data available
    Respiratory or skin sensitization
    No data available
    Germ cell mutagenicity
    No data available
    Carcinogenicity
    IARC: No ingredient of this product present at levels greater than or equal to 0.1% is
    identified as probable, possible or confirmed human carcinogen by IARC.
    Reproductive toxicity
    No data available
    Specific target organ toxicity - single exposure
    Inhalation - May cause respiratory irritation.
    Specific target organ toxicity - repeated exposure
    No data available
    Aspiration hazard
    No data available
    Additional Information
    RTECS: Not available
    To the best of our knowledge, the chemical, physical, and toxicological properties have not
    been thoroughly investigated
    ECOLOGICAL INFORMATION12.1 Toxicity
    Toxicity to fish LC50 - Poecilia reticulata (guppy) - 0,68 mg/l - 96,0 h
    12.2 Persistence and degradability
    No data available
    12.3 Bioaccumulative potential
    No data available
    12.4 Mobility in soil
    No data available 12.5 Results of PBT and vPvB assessment
    PBT/vPvB assessment not available as chemical safety assessment not required/not
    conducted
    12.6 Other adverse effects
    Very toxic to aquatic life
    DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
    Product
    Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or
    mix the material with a combustible solvent and burn in a chemical incinerator equipped
    with an afterburner and scrubber.
    Contaminated packaging
    Dispose of as unused product
    TRANSPORT INFORMATION14.1 UN number
    ADR/RID: 3077 IMDG: 3077 IATA: 3077
    14.2 UN proper shipping name
    ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,4-
    Dibromobenzene-d4)
    IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (1,4-
    Dibromobenzene-d4)
    IATA: Environmentally hazardous substance, solid, n.o.s. (1,4-Dibromobenzened<
    SB>4)
    14.3 Transport hazard class(es)
    ADR/RID: 9 IMDG: 9 IATA: 9
    14.4 Packaging group
    ADR/RID: III IMDG: III IATA: III
    14.5 Environmental hazards
    ADR/RID: yes IMDG Marine pollutant: yes IATA: yes
    14.6 Special precautions for user
    Further information
    EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and
    combination packagings containing inner packagings with Dangerous Goods > 5L for liquids
    or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of
    Class 9
    REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
    substance or mixture
    This material safety data sheet complies with the requirements of Regulation (EC) No.
    1907/2006
    OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. For lab use only!