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Ethanol-d1, anhydrous

99.5 atom%D

Item number	1097-1X100ML
CAS	925-93-9
Formula	C2H5DO
Molecular weight	47,07 g/mol
Quantity	1x100ml

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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 18.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	Ethanol-d1, anhydrous
Catalog No.:	1097-1X100ML
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Permoserstrasse 15 04318 Leipzig Germany Tel. +49 341 5295 183 Fax. +49 341 5295 182 E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225
Label elements
Pictogram	flamme flamme
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapour. Precautionary statement(s) P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. Supplemental Hazard Statements none 2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Synonyms : Ethan(ol-d) Ethyl alcohol-d1 Formula : C2DH5O Molecular weight : 47,08 g/mol CAS-No. : 925-93-9 EC-No. : 213-128-9 No components need to be disclosed according to the applicable regulations
Formula	C2H5DO
Molecular Weight (g/mol)	47.07
CAS-No.	925-93-9
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Impervious clothing, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -114 °C - lit f) Initial boiling point and boiling range 78 °C - lit. g) Flash point 14,0 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 19 %(V) Lower explosion limit: 3,3 %(V) k) Vapour pressure 59,5 hPa at 20,0 °C l) Vapour density No data available m) Relative density 0,806 g/mL at 25 °C n) Water solubility completely soluble o) Partition coefficient: n-octanol/water No data available p) Auto-ignition temperature 363,0 °C q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials Alkali metals, Ammonia, Oxidizing agents, Peroxides 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 7.060 mg/kg Remarks: Lungs, Thorax, or Respiration:Other changes. LC50 Inhalation - Rat - 10 h - 20000 ppm Skin corrosion/irritation Skin - Rabbit Result: No skin irritation - 24 h (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - Rabbit Result: Mild eye irritation - 24 h Respiratory or skin sensitisation No data available Germ cell mutagenicity No data available Carcinogenicity This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification. IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: Not available Heart - Irregularities - Based on Human Evidence
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish LC50 - Oncorhynchus mykiss (rainbow trout) - 13.000,00 mg/l - 96 h LC50 - Oncorhynchus mykiss (rainbow trout) - 10.400,00 mg/l - 96 h LC50 - Pimephales promelas (fathead minnow) - 15.300,00 mg/l - 96 h LC50 - other fish - 10.000,00 mg/l - 24 h Toxicity to daphnia and other aquatic invertebrates Remarks: No data available(ethyl [2]alcohol) 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION	14.1 UN number ADR/RID: 1170 IMDG: 1170 IATA: 1170 14.2 UN proper shipping name ADR/RID: ETHANOL IMDG: ETHANOL IATA: Ethanol 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. International Chemical Weapons Convention (CWC) Schedules of Toxic Chemicals and Precursors : Neither banned nor restricted REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : Neither banned nor restricted Regulation (EC) No 649/2012 of the European Parliament and the Council concerning the export and import of dangerous chemicals : Neither banned nor restricted REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). This product contains a substance listed on Annex XIV of the REACH Regulation (EC) Nr. 1907/2006. Listed substance / Sunset Date: After the sunset date the use of this substance requires either an authorization or can only be used for exempted uses, e.g. use in scientific research and development which includes routine analytics or use as intermediate. Regulation (EC) No 1005/2009 on substances that deplete the ozone layer : Neither banned nor restricted Regulation (EC) No 850/2004 on persistent organic pollutants : Neither banned nor restricted 15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!