Products

Nitromethane-d3

99.5 atom%D

Item number1133-1X5ML
CAS13031-32-8
FormulaCD3NO2
Molecular weight64,06 g/mol
Quantity 1x5ml
CoA / MSDSRetrieve CoA
Retrieve MSDS
Show Safety Data Sheet online
Nitromethane-d3

Price

Please log in.

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 29.03.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Nitromethane-d3
Catalog No.:1133-1X5ML
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Permoserstrasse 15

04318 Leipzig
Germany

Tel. +49 341 5295 183
Fax. +49 341 5295 182
E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 3), H226 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Carcinogenicity (Category 2), H351
Label elements
Pictogramflamme
flamme
GHS06 skull
skull
GHS08 silhouete
silhouete
2.2 Label elements Labelling according Regulation (EC) No 1272/2008
Signal word Danger
Hazard statement(s) H226 Flammable liquid and vapour. H302 Harmful if swallowed. H331 Toxic if inhaled. H351 Suspected of causing cancer.
Precautionary statement(s) P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor. P370 + P378 In case of fire: Use dry powder or dry sand to extinguish. P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances Synonyms : Trideuteronitromethane

Molecular weight : 64,06 g/mol CAS-No. : 13031-32-8 EC-No. : 235-892-2

Component: Nitromethane-d3
Classification: Flam. Liq. 3; Acute Tox. 4; H226, H302
Concentration: <= 100 %
FormulaCD3NO2
Molecular Weight (g/mol)64.06
CAS-No.13031-32-8
FIRST AID MEASURES4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. hygroscopic 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment

Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties a) Appearance Form: clear, liquid Colour: colourless b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point No data available f) Initial boiling point and boiling range 100 °C - lit. g) Flash point 35 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapour pressure 36,4 hPa at 20 °C l) Vapour density No data available m) Relative density 1,183 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: n-octanol/water No data available p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 940 mg/kg Remarks: (RTECS) LD50 Dermal - Rabbit - > 2.000 mg/kg Remarks: (IUCLID) Skin corrosion/irritation Skin - Rabbit Result: No skin irritation Remarks: (IUCLID) Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation Remarks: (IUCLID) Respiratory or skin sensitisation Sensitisation test: - Guinea pig Result: negative Remarks: (IUCLID) Germ cell mutagenicity Ames test Result: negative (IUCLID) Carcinogenicity IARC: 2B - Group 2B: Possibly carcinogenic to humans (Nitromethane-d3) Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Additional Information RTECS: Not available


Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Danio rerio (zebra fish) - 460 mg/l - 48 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 450 mg/l - 24 h (OECD Test Guideline 202)
Toxicity to algae IC50 - Desmodesmus subspicatus (green algae) - 36 mg/l - 72 h (OECD Test Guideline 201)
Toxicity to bacteria EC50 - Photobacterium phosphoreum - 5.621 mg/l - 30 min Remarks: (Lit.) 12.2 Persistence and degradability Biodegradability Result: - Not readily biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number ADR/RID: 1261 IMDG: 1261 IATA: 1261 14.2 UN proper shipping name ADR/RID: NITROMETHANE IMDG: NITROMETHANE IATA: Nitromethane Passenger Aircraft: Not permitted for transport 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.



15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!