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Cumene-d12

99 atom%D

Item number1057-1X5ML
CAS97732-82-6
FormulaC9D12
Molecular weight132,27 g/mol
Quantity 1X5ML
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Cumene-d12

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    Cumene-d12

    99 atom%D

    1057-1X1ML
    97732-82-6

    1X1ML

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    Cumene-d12

    99 atom%D

    1057-1X5ML
    97732-82-6

    1X5ML

    On request

    Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
    Classifications according to Regulation (EC) No 1272/2008.
    Printdate 27.07.2024
    IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
    Product name:Cumene-d12
    Catalog No.:1057-1X5ML
    Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
    uses: R&D
    Uses advised against:HPC Standards GmbH
    Permoserstrasse 15

    04318 Leipzig
    Germany

    Tel. +49 341 5295 183
    Fax. +49 341 5295 182
    E-mail: info@armar-europa.de
    HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
    Classification according to Regulation (EC) No 1272/2008
    Flammable liquids (Category 3), H226
    Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
    Aspiration hazard (Category 1), H304
    Long-term (chronic) aquatic hazard (Category 2), H411
    Label elements
    Pictogramflamme
    flamme
    GHS07 exclam
    exclam
    GHS08 silhouete
    silhouete
    GHS09 Aquatic-pollut-red
    Aquatic-pollut-red
    2.2 Label elements
    Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger
    Hazard statement(s)
    H226 Flammable liquid and vapor.
    H304 May be fatal if swallowed and enters airways.
    H335 May cause respiratory irritation.
    H411 Toxic to aquatic life with long lasting effects.
    Precautionary statement(s)
    P210 Keep away from heat, hot surfaces, sparks, open flames and
    other ignition sources. No smoking.
    P273 Avoid release to the environment.
    P301 + P310 + P331 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do
    NOT induce vomiting.
    Supplemental Hazard
    Statements
    none
    2.3 Other hazards
    This substance/mixture contains no components considered to be either persistent,
    bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
    levels of 0.1% or higher.
    May form explosive peroxides.
    COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
    Synonyms : Isopropylbenzene
    Formula : C9H12
    Molecular weight : 120,19 g/mol
    CAS-No. : 98-82-8
    EC-No. : 202-704-5
    Index-No. : 601-024-00-X
    Component Classification Concentration
    cumene
    Flam. Liq. 3; STOT SE 3;
    Asp. Tox. 1; Aquatic
    Chronic 2; H226, H335,
    H304, H411
    <= 100 %
    FormulaC9D12
    Molecular Weight (g/mol)132.27
    CAS-No.97732-82-6
    FIRST AID MEASURES4.1 Description of first-aid measures
    General advice
    Consult a physician. Show this material safety data sheet to the doctor in attendance If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration.
    Consult a physician.
    In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
    In case of eye contact
    Flush eyes with water as a precaution.
    If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
    mouth with water. Consult a physician.
    4.2 Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section
    2.2) and/or in section 11
    4.3 Indication of any immediate medical attention and special treatment needed
    No data available
    FIRE-FIGHTING MEASURES5.1 Extinguishing media
    Suitable extinguishing media
    Dry powder Dry sand
    Unsuitable extinguishing media
    Do NOT use water jet.
    5.2 Special hazards arising from the substance or mixture
    Carbon oxides
    5.3 Advice for firefighters
    Wear self-contained breathing apparatus for firefighting if necessary.
    5.4 Further information
    Use water spray to cool unopened containers
    ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate
    ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of
    vapors accumulating to form explosive concentrations. Vapors can accumulate in low
    areas.
    For personal protection see section 8.
    6.2 Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
    Discharge into the environment must be avoided.
    6.3 Methods and materials for containment and cleaning up
    Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
    earth, diatomaceous earth, vermiculite) and place in container for disposal according to
    local / national regulations (see section 13). 6.4 Reference to other sections
    For disposal see section 13.
    HANDLING AND STORAGE7.1 Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapor or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
    electrostatic charge.
    For precautions see section 2.2.
    7.2 Conditions for safe storage, including any incompatibilities
    Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
    Recommended storage temperature 2 - 8 °C
    Store under inert gas.
    7.3 Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
    EXPOSURE CONTROLS/PERSONAL PROTECTION.1 Control parameters8.2 Exposure controlsEngineering measuresTechnical measures and appropriate working operations should be given priority over the use of personal protective equipment.See section 7.1.Individual protection measuresProtective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled. The chemical resistance of the protective equipment should be enquired at the respective supplier.Hygiene measuresImmediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance.Eye/face protection Safety glasses
    Hand protection
    The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374. This recommendation applies only to the product stated in the safety data sheet supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves. Other protective equipment:Flame retardant antistatic protective clothingRespiratory protectionrequired when vapours/aerosols are generated.Recommended Filter type:Filter A (acc. to DIN 3181) for vapours of organic compoundsThe entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.Environmental exposure controls Do not empty into drains. Risk of explosion.
    PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
    a) Appearance Form: liquid, clear
    Color: colorless
    b) Odor No data available
    c) Odor Threshold No data available
    d) pH No data available
    e) Melting
    point/freezing point
    Melting point/range: -96 °C - lit.
    f) Initial boiling point
    and boiling range
    152 - 154 °C - lit.
    g) Flash point 31,0 °C - closed cup
    h) Evaporation rate No data available
    i) Flammability (solid,
    gas)
    No data available
    j) Upper/lower
    flammability or
    explosive limits
    Upper explosion limit: 6,5 %(V)
    Lower explosion limit: 0,9 %(V)
    k) Vapor pressure 10,7 hPa at 20,0 °C
    l) Vapor density No data available m) Relative density 0,864 g/mL at 25 °C
    n) Water solubility 0,06 g/l at 25 °C - slightly soluble
    o) Partition coefficient:
    n-octanol/water
    log Pow: 3,55 at 23 °C
    p) Autoignition
    temperature
    425,0 °C
    q) Decomposition
    temperature
    No data available
    r) Viscosity No data available
    s) Explosive properties No data available
    t) Oxidizing properties No data available
    9.2 Other safety information
    Surface tension 27,69 mN/m at 25 °C
    STABILITY AND REACTIVITY10.1 Reactivity
    No data available
    10.2 Chemical stability
    Stable under recommended storage conditions.
    Stable under recommended storage conditions.
    10.3 Possibility of hazardous reactions
    No data available
    10.4 Conditions to avoid
    Heat, flames and sparks.
    10.5 Incompatible materials
    Strong oxidizing agents
    10.6 Hazardous decomposition products
    Hazardous decomposition products formed under fire conditions. - Carbon oxides
    Other decomposition products - No data available
    In the event of fire: see section 5
    TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
    Acute toxicity
    No data available
    Skin corrosion/irritation
    Skin - Rabbit
    Result: No skin irritation
    (OECD Test Guideline 404)
    Drying-out effect resulting in rough and chapped skin Serious eye damage/eye irritation
    Eyes - Rabbit
    Result: No eye irritation - 72 h
    (OECD Test Guideline 405)
    Respiratory or skin sensitization
    Maximization Test - Guinea pig
    Result: negative
    (OECD Test Guideline 406)
    Germ cell mutagenicity
    Mutagenicity (mammal cell test): chromosome aberration.
    Chinese hamster ovary cells
    Result: negative
    Ames test
    Salmonella typhimurium
    Result: negative
    In vitro mammalian cell gene mutation test
    Chinese hamster ovary cells
    Result: negative
    unscheduled DNA synthesis assay
    rat hepatocytes
    Result: negative
    OECD Test Guideline 474
    Mouse - male and female - Red blood cells (erythrocytes)
    Result: negative
    OECD Test Guideline 474
    Rat - male - Bone marrow
    Result: Positive results were obtained in some in vivo tests.
    Carcinogenicity
    IARC: 2B - Group 2B: Possibly carcinogenic to humans (cumene)
    Reproductive toxicity
    No data available Specific target organ toxicity - single exposure
    Inhalation - May cause respiratory irritation. - Respiratory Tract
    Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
    Acute oral toxicity - gastric pain, Vomiting
    Acute inhalation toxicity - mucosal irritations, Cough, Shortness of breath, Headache,
    Nausea, Vomiting, Possible damages:, damage of respiratory tract
    Specific target organ toxicity - repeated exposure
    No data available
    Aspiration hazard
    Aspiration may cause pulmonary edema and pneumonitis.
    Additional Information
    RTECS: GR8575000
    narcosis, Central nervous system depression, Dermatitis, Gastrointestinal disturbance,
    Damage to the lungs., Liver injury may occur., Kidney injury may occur.
    To the best of our knowledge, the chemical, physical, and toxicological properties have not
    been thoroughly investigated.
    After uptake of large quantities: somnolence, Dizziness, narcosis
    Effect potentiated by: ethanol
    Handle in accordance with good industrial hygiene and safety practice
    ECOLOGICAL INFORMATION12.1 Toxicity
    Toxicity to fish flow-through test LC50 - Cyprinodon variegatus (sheepshead
    minnow) - 4,7 mg/l - 96 h
    (US-EPA)
    Toxicity to daphnia
    and other aquatic
    invertebrates
    static test EC50 - Daphnia magna (Water flea) - 2,14 mg/l - 48 h
    (OECD Test Guideline 202)
    Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - 2,01
    mg/l - 72 h
    (OECD Test Guideline 201)
    Toxicity to bacteria static test EC50 - activated sludge - > 2.000 mg/l - 3 h
    (OECD Test Guideline 209)
    12.2 Persistence and degradability
    Biodegradability aerobic - Exposure time 20 d
    Result: 70 % - Readily biodegradable.
    Remarks: (ECHA)
    12.3 Bioaccumulative potential
    No data available
    12.4 Mobility in soil
    No data available
    12.5 Results of PBT and vPvB assessment
    This substance/mixture contains no components considered to be either persistent,
    bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
    levels of 0.1% or higher.
    12.6 Other adverse effects
    Toxic to aquatic life with long lasting effects.
    Discharge into the environment must be avoided
    DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
    Product
    Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
    must be disposed of in accordance with the Directive on waste 2008/98/EC as well as
    other national and local regulations. Leave chemicals in original containers. No mixing
    with other waste. Handle uncleaned containers like the product itself.
    Contaminated packaging
    Dispose of as unused product.
    TRANSPORT INFORMATION14.1 UN number
    ADR/RID: 1918 IMDG: 1918 IATA: 1918
    14.2 UN proper shipping name
    ADR/RID: ISOPROPYLBENZENE
    IMDG: ISOPROPYLBENZENE
    IATA: Isopropylbenzene
    14.3 Transport hazard class(es)
    ADR/RID: 3 IMDG: 3 IATA: 3
    14.4 Packaging group
    ADR/RID: III IMDG: III IATA: III
    14.5 Environmental hazards
    ADR/RID: yes IMDG Marine pollutant: yes IATA: no
    14.6 Special precautions for user
    No data available
    REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
    substance or mixture
    This material safety data sheet complies with the requirements of Regulation (EC) No.
    1907/2006.
    REACH - Restrictions on the manufacture,
    placing on the market and use of certain
    dangerous substances, preparations and articles
    (Annex XVII)
    :
    REACH - Restrictions on the manufacture,
    placing on the market and use of certain
    dangerous substances, preparations and articles
    (Annex XVII)
    :
    15.2 Chemical Safety Assessment
    For this product a chemical safety assessment was not carried out
    OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. For lab use only!