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1-Bromobutane-d9

99 atom%D

Item number1047-1X1G
CAS98195-36-9
FormulaC4BrD9
Molecular weight146,07 g/mol
Quantity 1X1G
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1-Bromobutane-d9

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    1-Bromobutane-d9

    99 atom%D

    1047-1X1G
    98195-36-9

    1X1G

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    Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
    Classifications according to Regulation (EC) No 1272/2008.
    Printdate 27.07.2024
    IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
    Product name:1-Bromobutane-d9
    Catalog No.:1047-1X1G
    Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
    uses: R&D
    Uses advised against:HPC Standards GmbH
    Permoserstrasse 15

    04318 Leipzig
    Germany

    Tel. +49 341 5295 183
    Fax. +49 341 5295 182
    E-mail: info@armar-europa.de
    HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture
    Classification according to Regulation (EC) No 1272/2008
    Flammable liquids (Category 2), H225
    Skin irritation (Category 2), H315
    Eye irritation (Category 2), H319
    Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
    Long-term (chronic) aquatic hazard (Category 2), H411
    Label elements
    Pictogramflamme
    flamme
    GHS07 exclam
    exclam
    GHS09 Aquatic-pollut-red
    Aquatic-pollut-red
    2.2 Label elements
    Labelling according Regulation (EC) No 1272/2008
    Signal word Danger
    Hazard statement(s)
    H225 Highly flammable liquid and vapour.
    H315 Causes skin irritation.
    H319 Causes serious eye irritation.
    H335 May cause respiratory irritation.
    H411 Toxic to aquatic life with long lasting effects.
    Precautionary statement(s)
    P210 Keep away from heat, hot surfaces, sparks, open flames and
    other ignition sources. No smoking.
    P273 Avoid release to the environment.
    P302 + P352 IF ON SKIN: Wash with plenty of water.
    P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes.
    Remove contact lenses, if present and easy to do. Continue
    rinsing.
    Supplemental Hazard
    Statements
    none
    2.3 Other hazards
    This substance/mixture contains no components considered to be either persistent,
    bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
    levels of 0.1% or higher.
    COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances
    Synonyms : Butyl bromide
    Molecular weight : 137.02 g/mol
    CAS-No. : 109-65-9
    EC-No. : 203-691-9
    Component Classification Concentration
    1-Bromobutane
    Flam. Liq. 2; Skin Irrit. 2;
    Eye Irrit. 2; STOT SE 3;
    Aquatic Chronic 2; H225,
    H315, H319, H335, H411
    <= 100 %
    FormulaC4BrD9
    Molecular Weight (g/mol)146.07
    CAS-No.98195-36-9
    FIRST AID MEASURES4.1 Description of first aid measures
    General advice
    Consult a physician. Show this safety data sheet to the doctor in attendance.
    If inhaled
    If breathed in, move person into fresh air. If not breathing, give artificial respiration.
    Consult a physician.
    In case of skin contact
    Wash off with soap and plenty of water. Consult a physician.
    In case of eye contact
    Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
    If swallowed
    Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse
    mouth with water. Consult a physician.
    4.2 Most important symptoms and effects, both acute and delayed
    The most important known symptoms and effects are described in the labelling (see section
    2.2) and/or in section 11
    4.3 Indication of any immediate medical attention and special treatment needed
    No data available
    FIRE-FIGHTING MEASURES5.1 Extinguishing media
    Suitable extinguishing media
    Dry powder Dry sand
    Unsuitable extinguishing media
    Do NOT use water jet.
    5.2 Special hazards arising from the substance or mixture
    Carbon oxides, Hydrogen bromide gas
    5.3 Advice for firefighters
    Wear self-contained breathing apparatus for firefighting if necessary.
    5.4 Further information
    Use water spray to cool unopened containers.
    ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure
    adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.
    Beware of vapours accumulating to form explosive concentrations. Vapours can
    accumulate in low areas.
    For personal protection see section 8.
    6.2 Environmental precautions
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
    Discharge into the environment must be avoided.
    6.3 Methods and materials for containment and cleaning up
    Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand,
    earth, diatomaceous earth, vermiculite) and place in container for disposal according to
    local / national regulations (see section 13).
    6.4 Reference to other sections
    For disposal see section 13.
    HANDLING AND STORAGE7.1 Precautions for safe handling
    Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.
    Keep away from sources of ignition - No smoking.Take measures to prevent the build up of
    electrostatic charge.
    For precautions see section 2.2.
    7.2 Conditions for safe storage, including any incompatibilities
    Keep container tightly closed in a dry and well-ventilated place. Containers which are
    opened must be carefully resealed and kept upright to prevent leakage. Store in cool place.
    7.3 Specific end use(s)
    Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
    EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters
    Components with workplace control parameters
    Contains no substances with occupational exposure limit values.
    8.2 Exposure controls
    Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands
    before breaks and at the end of workday.
    Personal protective equipment
    Eye/face protection
    Face shield and safety glasses Use equipment for eye protection tested and
    approved under appropriate government standards such as NIOSH (US) or EN
    166(EU).
    Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove
    removal technique (without touching gloves outer surface) to avoid skin contact
    with this product. Dispose of contaminated gloves after use in accordance with
    applicable laws and good laboratory practices. Wash and dry hands.
    The selected protective gloves have to satisfy the specifications of Regulation (EU)
    2016/425 and the standard EN 374 derived from it.
    Body Protection
    Impervious clothing, Flame retardant antistatic protective clothing., The type of
    protective equipment must be selected according to the concentration and amount
    of the dangerous substance at the specific workplace.
    Respiratory protection
    Where risk assessment shows air-purifying respirators are appropriate use a fullface
    respirator with multi-purpose combination (US) or type ABEK (EN 14387)
    respirator cartridges as a backup to engineering controls. If the respirator is the sole
    means of protection, use a full-face supplied air respirator. Use respirators and
    components tested and approved under appropriate government standards such as
    NIOSH (US) or CEN (EU).
    Control of environmental exposure
    Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
    Discharge into the environment must be avoided.
    PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties
    a) Appearance Form: clear, liquid
    Colour: light brown
    b) Odour No data available
    c) Odour Threshold No data available
    d) pH No data available
    e) Melting point/freezing point Melting point/range: -112 °C - lit.
    f) Initial boiling point and boiling range 100 - 104 °C - lit.
    g) Flash point 10 °C - closed cup
    h) Evaporation rate No data available
    i) Flammability (solid, gas) No data available
    j) Upper/lower flammability or explosive limits
    Upper explosion limit: 6.6 %(V)
    Lower explosion limit: 2.8 %(V)
    k) Vapour pressure 200 hPa at 50 °C 53 hPa at 25 °C
    l) Vapour density 4.73 - (Air = 1.0)
    m) Relative density 1.276 g/mL at 25 °C
    n) Water solubility No data available
    o) Partition coefficient: n-octanol/water log Pow: 2.75
    p) Auto-ignition temperature No data available
    q) Decomposition temperature No data available
    r) Viscosity No data available
    s) Explosive properties No data available
    t) Oxidizing properties No data available
    9.2 Other safety information
    Relative vapour density 4.73 - (Air = 1.0)
    STABILITY AND REACTIVITY10.1 Reactivity
    No data available
    10.2 Chemical stability
    Stable under recommended storage conditions.
    10.3 Possibility of hazardous reactions
    No data available
    10.4 Conditions to avoid
    Heat, flames and sparks.
    10.5 Incompatible materials
    Strong oxidizing agents, Strong bases, Magnesium, Potassium, Sodium/sodium oxides
    10.6 Hazardous decomposition products
    Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen
    bromide gas
    Other decomposition products - No data available
    In the event of fire: see section 5
    TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects
    Acute toxicity
    LD50 Oral - Rat - 2,761 mg/kg
    Remarks: Behavioral:Somnolence (general depressed activity). Behavioral:Tremor.
    Behavioral:Ataxia.
    Inhalation: No data available
    Dermal: No data available
    Skin corrosion/irritation
    Irritating to skin. The preceding data, or interpretation of data, was determined using
    Quantitative Structure Activity Relationship (QSAR) modeling.
    Serious eye damage/eye irritation
    Moderate eye irritation The preceding data, or interpretation of data, was determined using
    Quantitative Structure Activity Relationship (QSAR) modeling.
    Respiratory or skin sensitisation
    No data available
    Germ cell mutagenicity
    No data available
    Carcinogenicity
    IARC: No component of this product present at levels greater than or equal to 0.1% is
    identified as probable, possible or confirmed human carcinogen by IARC.
    Reproductive toxicity
    No data available
    Specific target organ toxicity - single exposure
    Inhalation - May cause respiratory irritation.
    The preceding data, or interpretation of data, was determined using Quantitative Structure
    Activity Relationship (QSAR) modeling.
    Specific target organ toxicity - repeated exposure
    No data available
    Aspiration hazard
    No data available
    Additional Information
    RTECS: EJ6225000
    Cough, Shortness of breath, Headache, Nausea, Vomiting
    To the best of our knowledge, the chemical, physical, and toxicological properties have not
    been thoroughly investigated.
    ECOLOGICAL INFORMATION12.1 Toxicity
    Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 36.7 mg/l - 96.0 h
    12.2 Persistence and degradability
    Biodegradability Result: 1 % - Not readily biodegradable.
    12.3 Bioaccumulative potential
    No data available
    12.4 Mobility in soil
    No data available
    12.5 Results of PBT and vPvB assessment
    This substance/mixture contains no components considered to be either persistent,
    bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at
    levels of 0.1% or higher.
    12.6 Other adverse effects
    Toxic to aquatic life with long lasting effects.
    DISPOSAL CONSIDERATIONS13.1 Waste treatment methods
    Product
    Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material
    must be disposed of in accordance with the Directive on waste 2008/98/EC as well as
    other national and local regulations. Leave chemicals in original containers. No mixing
    with other waste. Handle uncleaned containers like the product itself.
    Contaminated packaging
    Dispose of as unused product.
    TRANSPORT INFORMATION14.1 UN number
    ADR/RID: 1126 IMDG: 1126 IATA: 1126
    14.2 UN proper shipping name
    ADR/RID: 1-BROMOBUTANE
    IMDG: 1-BROMOBUTANE
    IATA: 1-Bromobutane
    14.3 Transport hazard class(es)
    ADR/RID: 3 IMDG: 3 IATA: 3
    14.4 Packaging group
    ADR/RID: II IMDG: II IATA: II
    14.5 Environmental hazards
    ADR/RID: yes IMDG Marine pollutant: yes IATA: no
    14.6 Special precautions for user
    No data available
    REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the
    substance or mixture
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
    REACH - Restrictions on the manufacture,
    placing on the market and use of certain
    dangerous substances, preparations and articles
    (Annex XVII)
    :
    REACH - Restrictions on the manufacture,
    placing on the market and use of certain
    dangerous substances, preparations and articles
    (Annex XVII)
    :
    15.2 Chemical safety assessment
    For this product a chemical safety assessment was not carried out
    OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
    guarantee of the properties of the product. For lab use only!