Products

Hexamethylphosphoricacid triamide-d18

99.5 atom%D

Item number1111-1X1ML
CAS51219-90-0
FormulaC6D18N3OP
Molecular weight197,31 g/mol
Quantity 1x1ml
Hexamethylphosphoricacid triamide-d18

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 29.02.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Hexamethylphosphoricacid triamide-d18
Catalog No.:1111-1X1ML
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Permoserstrasse 15

04318 Leipzig
Germany

Tel. +49 341 5295 183
Fax. +49 341 5295 182
E-mail: info@armar-europa.de
HAZARDS IDENTIFICATIONThis chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200).
Classification Acute toxicity - Oral Category 3 Acute toxicity - Dermal Category 3 Acute toxicity - Inhalation (Dusts/Mists) Category 3
Label elements
PictogramGHS06 skull
skull
Label elements Signal word Danger
Hazard statements
Toxic if swallowed Toxic in contact with skin Toxic if inhaled
Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Wear protective gloves/protective clothing/eye protection/face protection
Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area
Precautionary Statements - Response
IF exposed or concerned: Get medical advice/attention
IF ON SKIN: Wash with plenty of soap and water Call a POISON CENTER or doctor/physician if you feel unwell Remove/Take off immediately all contaminated clothing Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a POISON CENTER or doctor/physician IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth
Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant
Hazards not otherwise classified (HNOC) Hazards not otherwise classified (HNOC) Not applicable
COMPOSITION/INFORMATION ON INGREDIENTSComponent: Hexamethylphosphortriamid e-D18
Classification: Acute Tox. 3 (H301) Acute Tox. 3 (H311)Acute Tox. 3 (H331)
Concentration: <=100%
FormulaC6D18N3OP
Molecular Weight (g/mol)197.31
CAS-No.51219-90-0
FIRST AID MEASURESFirst Aid Measures General advice Consult a physician if necessary. Remove to fresh air. Eye contact Wash with plenty of water. Skin Contact Wash skin with soap and water. Inhalation Remove to fresh air If breathing is difficult, give oxygen If not breathing, give artificial respiration Ingestion Never give anything by mouth to an unconscious person. Clean mouth with water.
Most important symptoms and effects, both acute and delayed Symptoms No information available.
Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically.
FIRE-FIGHTING MEASURESSuitable Extinguishing Media Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media None.
Specific hazards arising from the chemical Specific hazards arising from the chemical No information available. Hazardous combustion products Carbon oxides. Nitrogen oxides (NOx).
Explosion data Sensitivity to Mechanical Impact No information available. Sensitivity to Static Discharge No information available.
Protective equipment and precautions for firefighters Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.

ACCIDENTAL RELEASE MEASURESPersonal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas.
Environmental precautions Environmental precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers.
HANDLING AND STORAGEPrecautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice.
Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store at room temperature. Incompatible materials None known based on information supplied.
EXPOSURE CONTROLS/PERSONAL PROTECTIONControl parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies.
Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems
Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and Body Protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
PHYSICAL AND CHEMICAL PROPERTIESPhysical State liquid Appearance No information available Odor No information available
Property Values pH No information available Melting point/freezing point No information available Boiling point No information available Flash point No information available Density No information available Evaporation rate No information available Upper flammability limits No information available Lower flammability limit No information available Vapor pressure No information available Vapor density No information available Specific gravity No information available Water solubility No information available Solubility in other solvents No information available Partition coefficient No information available Autoignition temperature No information available Decomposition temperature No information available Kinematic viscosity No information available Explosive properties No information available Oxidizing properties No information available

STABILITY AND REACTIVITYReactivity Not applicable
Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous polymerization No information available. Conditions to avoid Extremes of temperature and direct sunlight. Incompatible materials Strong oxidizing agents. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx)
TOXICOLOGICAL INFORMATIONInformation on likely routes of exposure Inhalation No data available. Eye contact No data available. Skin Contact No data available. Ingestion No data available.
Information on toxicological effects Symptoms No information available.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity No information available.
Numerical measures of toxicity - Product Information Unknown acute toxicity No information available The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 100 mg/kg ATEmix (dermal) 300 mg/kg ATEmix (inhalation-dust/mist) 0.5 mg/l
ECOLOGICAL INFORMATIONEcotoxicity May cause long lasting harmful effects to aquatic life
100% of the mixture consists of components(s) of unknown hazards to the aquatic environment.
Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available.
DISPOSAL CONSIDERATIONSDisposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container.
TRANSPORT INFORMATIONDOT UN/ID no UN2810 Hazard Class 6.1 Packing Group III Proper shipping name Poison B, liquid, n.o.s Description UN2810, Poison B, liquid, n.o.s, 6.1, III Emergency Response Guide Number 153
IMDG UN/ID no UN2810 Hazard Class 6.1 Packing Group III Proper shipping name Toxic liquid, organic, n.o.s. Description UN2810, Toxic liquid, organic, n.o.s., 6.1, III Special Provisions IB3, T7, TP1, TP28 EmS-No F-A, S-A
IATA UN/ID no UN2810 Hazard Class 6.1 Packing Group III Proper shipping name Toxic liquid, organic, n.o.s.* Description UN2810, Toxic liquid, organic, n.o.s.*, 6.1, III
REGULATORY INFORMATIONInternational Inventories
All of the components in the product are on the following Inventory lists Europe (EINECS/ELINCS/NLP)
US Federal Regulations
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372.
SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive hazard No
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).
US State Regulations
California Proposition 65 This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations This product does not contain any substances regulated by state right-to-know regulations

OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!