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N,N-Dimethylacetamide-d9

99 atom%D

Item number	1080-1X1ML
CAS	116570-81-9
Formula	C4D9NO
Molecular weight	96,18 g/mol
Quantity	1x1ml
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Safety Data Sheet	according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 20.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:	N,N-Dimethylacetamide-d9
Catalog No.:	1080-1X1ML
Relevant identified uses of the substance or mixture	Identified: Laboratory chemical uses: R&D
Uses advised against:	HPC Standards GmbH Permoserstrasse 15 04318 Leipzig Germany Tel. +49 341 5295 183 Fax. +49 341 5295 182 E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION	2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Inhalation (Category 4), H332 Acute toxicity, Dermal (Category 4), H312 Eye irritation (Category 2), H319 Reproductive toxicity (Category 1B), H360D
Label elements
Pictogram	GHS07 exclam exclam GHS08 silhouete silhouete
	2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H312 + H332 Harmful in contact with skin or if inhaled. H319 Causes serious eye irritation. H360D May damage the unborn child. Precautionary statement(s) P201 Obtain special instructions before use. P280 Wear protective gloves/ protective clothing. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water. Call a POISON CENTER/doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none Restricted to professional users. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Rapidly absorbed through skin.
COMPOSITION/INFORMATION ON INGREDIENTS	3.1 Substances Formula : C4H9NO Molecular weight : 87,12 g/mol CAS-No. : 127-19-5 EC-No. : 204-826-4 Index-No. : 616-011-00-4 Component Classification Concentration N,N-Dimethylacetamide Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH) Acute Tox. 3; Acute Tox. 4; Eye Irrit. 2; Repr. 1B; H331, H312, H319, H360D <= 100 %
Formula	C4D9NO
Molecular Weight (g/mol)	96.18
CAS-No.	116570-81-9
FIRST AID MEASURES	4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES	5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) Combustible liquid. 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES	6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE	7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist.Avoid exposure - obtain special instructions before use. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Store under inert gas. Hygroscopic. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION	Control parameters Exposure Guidelines This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and Body Protection Wear protective gloves and protective clothing. Respiratory protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
PHYSICAL AND CHEMICAL PROPERTIES	9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Colour: colourless b) Odour Ammonia odor c) Odour Threshold No data available d) pH 4 at 200 g/l at 20 °C e) Melting point/freezing point Melting point/freezing point: -20 °C f) Initial boiling point and boiling range 166 °C at 1.013 hPa g) Flash point 64 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 11,5 %(V) Lower explosion limit: 1,8 %(V) k) Vapour pressure 2 hPa at 21,7 °C 11,8 hPa at 50 °C l) Vapour density 3,01 - (Air = 1.0) m) Relative density 0,94 g/cm3 at 20 °C n) Water solubility 1.000 g/l at 20 °C - completely miscible o) Partition coefficient: n-octanol/water log Pow: -0,77 p) Auto-ignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Dissociation constant -0,19 at 25 °C Relative vapour density 3,01 - (Air = 1.0)
STABILITY AND REACTIVITY	10.1 Reactivity No data available 10.2 Chemical stability hygroscopic Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION	11.1 Information on toxicological effects Acute toxicity LC50 Inhalation - Rat - 4 h - 2,21 mg/l Remarks: Nutritional and Gross Metabolic:Weight loss or decreased weight gain. (RTECS) Skin corrosion/irritation Skin - Rabbit Result: No skin irritation (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - Rabbit Result: Irritating to eyes. (OECD Test Guideline 405) Respiratory or skin sensitisation Local lymph node assay (LLNA) - Guinea pig Result: negative (OECD Test Guideline 429) Germ cell mutagenicity Ames test Salmonella typhimurium Result: negative Mutagenicity (mammal cell test): chromosome aberration. Human lymphocytes Result: negative In vitro mammalian cell gene mutation test Chinese hamster lung cells Result: negative Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity May damage the unborn child Specific target organ toxicity - single exposure No data available Acute oral toxicity - Irritations of mucous membranes in the mouth, pharynx, oesophagus and gastrointestinal tract. Acute inhalation toxicity - Possible damages:, mucosal irritations Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information Repeated dose toxicity - Rat - male and female - Oral - 2 yr - No observed adverse effect level - 100 - 300 mg/kg - Lowest observed adverse effect level - 300 - 1.000 mg/kg RTECS: AB7700000 impaired judgment, emotional instability, toxic psychosis, nystagmus, dysarthria, Ataxia. To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. After absorption of toxic quantities: Nausea, Vomiting, inebriation, muscle twitching, hallucinations, Diarrhoea, lack of appetite, narcosis, Coma Damage to: Liver, Kidney, Central nervous system Other dangerous properties can not be excluded. This substance should be handled with particular care. Liver - Irregularities - Based on Human Evidence
ECOLOGICAL INFORMATION	12.1 Toxicity Toxicity to fish static test LC50 - Leuciscus idus (Golden orfe) - > 500 mg/l - 96 h (DIN 38412 T15) Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - > 500 mg/l - 48 h (Regulation (EC) No. 440/2008, Annex, C.2) Toxicity to algae static test ErC50 - Desmodesmus subspicatus (green algae) - > 500 mg/l - 72 h (DIN 38412) Toxicity to bacteria static test EC10 - activated sludge - > 1.995 mg/l - 30 min (OECD Test Guideline 209) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 70 % - Readily biodegradable. (OECD Test Guideline 301C) Remarks: The 10 day time window criterion is not fulfilled. 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS	13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product
TRANSPORT INFORMATION	14.1 UN number ADR/RID: - IMDG: - IATA: - 14.2 UN proper shipping name ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods 14.3 Transport hazard class(es) ADR/RID: - IMDG: - IATA: - 14.4 Packaging group ADR/RID: - IMDG: - IATA: - 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION	15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : N,N-Dimethylacetamide REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : N,N-Dimethylacetamide 15.2 Chemical safety assessment A Chemical Safety Assessment has been carried out for this substance
OTHER INFORMATION	The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only!