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Nitrobenzene-d5

99.5 atom%D

Item number1131-1X5ML
CAS4165-60-0
FormulaC6D5NO2
Molecular weight128,14 g/mol
Quantity 1x5ml
Nitrobenzene-d5

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 16.04.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Nitrobenzene-d5
Catalog No.:1131-1X5ML
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Permoserstrasse 15

04318 Leipzig
Germany

Tel. +49 341 5295 183
Fax. +49 341 5295 182
E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 3), H301 Acute toxicity, Inhalation (Category 3), H331 Acute toxicity, Dermal (Category 3), H311 Carcinogenicity (Category 2), H351 Reproductive toxicity (Category 1B), H360F Specific target organ toxicity - repeated exposure (Category 1), Blood, H372 Long-term (chronic) aquatic hazard (Category 3), H412
Label elements
PictogramGHS06 skull
skull
GHS08 silhouete
silhouete
2.2 Label elements Labelling according Regulation (EC) No 1272/2008
Signal word Danger
Hazard statement(s) H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled. H351 Suspected of causing cancer. H360F May damage fertility. H372 Causes damage to organs (Blood) through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s) P201 Obtain special instructions before use. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P310 + P330 IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P403 + P233 Store in a well-ventilated place. Keep container tightly closed.
Supplemental Hazard Statements none
Restricted to professional users. Restricted to professional users. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances Synonyms : Pentadeuteronitrobenzene

Formula : C6D5NO2 Molecular weight : 128,15 g/mol CAS-No. : 4165-60-0 EC-No. : 224-014-3

Component: nitrobenzene-d5
Classification: Acute Tox. 3; Carc. 2; Repr. 1B; STOT RE 1; Aquatic Chronic 3; H301, H331, H311, H351, H360F, H372, H412
Concentration: <= 100 %
FormulaC6D5NO2
Molecular Weight (g/mol)128.14
CAS-No.4165-60-0
FIRST AID MEASURES4.1 Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Flush eyes with water as a precaution. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media Do NOT use water jet. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Nitrogen oxides (NOx) 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Wear respiratory protection. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Personal protective equipment

Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odor No data available c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point No data available f) Initial boiling point and boiling range 88 °C at 16 hPa - lit. g) Flash point 88 °C h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 40 %(V) Lower explosion limit: 1,8 %(V) k) Vapor pressure No data available l) Vapor density No data available m) Relative density 1,253 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: n-octanol/water No data available p) Autoignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Nitrogen oxides (NOx) Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute toxicity absorption LC50 Inhalation - Rat - 4 h - 2,8 mg/l Remarks: (RTECS) Inhalation: absorption Dermal: absorption LD50 Dermal - Rabbit - 760 mg/kg Remarks: (ECHA) The value is given in analogy to the following substances: Skin corrosion/irritation Skin - Rabbit Result: No skin irritation Remarks: (ECHA) The value is given in analogy to the following substances: Serious eye damage/eye irritation Eyes - Rabbit Result: No eye irritation Remarks: (ECHA) The value is given in analogy to the following substances: Respiratory or skin sensitization Sensitisation test: - Guinea pig Result: negative Remarks: (IUCLID) The value is given in analogy to the following substances: Local lymph node assay (LLNA) - Mouse Result: Does not cause skin sensitization. (OECD Test Guideline 429) Remarks: The value is given in analogy to the following substances: Germ cell mutagenicity OECD Test Guideline 474 Mouse - male and female - Bone marrow Result: negative The value is given in analogy to the following substances: OECD Test Guideline 486 Rat - male - Liver cells Result: negative The value is given in analogy to the following substances: Carcinogenicity Suspected of causing cancer. IARC: 2B - Group 2B: Possibly carcinogenic to humans (nitrobenzene-d5) Reproductive toxicity May damage fertility. Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. - Blood Aspiration hazard Additional Information RTECS: Not available


Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer., Exposure to and/or consumption of alcohol may increase toxic effects., Nausea, Headache, Vomiting, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.
After absorption: agitation, CNS disorders, Drowsiness, Unconsciousness, collapse, Coma Symptoms may be delayed. Effect potentiated by: ethanol Other information The following applies to aromatic nitro compounds in general: systemic effect: methaemoglobinaemia with headache, cardiac dysrhythmias, drop in blood pressure, dyspnoea, and spasms; principal sign: cyanosis (blue discolouration of the blood). Further data: Other dangerous properties can not be excluded. This substance should be handled with particular care.
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish flow-through test LC50 - Danio rerio (zebra fish) - 92,2 mg/l - 96 h (OECD Test Guideline 203) Remarks: The value is given in analogy to the following substances:

Toxicity to daphnia and other aquatic invertebrates
static test EC50 - Daphnia magna (Water flea) - 35 mg/l - 48 h (OECD Test Guideline 202) Remarks: The value is given in analogy to the following substances:
Toxicity to algae IC5 - Scenedesmus quadricauda (Green algae) - 33 mg/l Remarks: (Lit.)
IC50 - Chlorella pyrenoidosa - 18 mg/l - 96 h Remarks: (IUCLID)
static test ErC50 - Chlorella pyrenoidosa - 18 mg/l - 96 h (OECD Test Guideline 201) Remarks: The value is given in analogy to the following substances:
Toxicity to bacteria static test EC20 - activated sludge - 1.000 mg/l - 30 min (OECD Test Guideline 209) Remarks: The value is given in analogy to the following substances: 12.2 Persistence and degradability Biodegradability Result: 3,3 % - Not readily biodegradable. (OECD Test Guideline 301C) Remarks: The value is given in analogy to the following substances: 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Toxic to aquatic life with long lasting effects. Discharge into the environment must be avoided.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number ADR/RID: 1662 IMDG: 1662 IATA: 1662 14.2 UN proper shipping name ADR/RID: NITROBENZENE IMDG: NITROBENZENE IATA: Nitrobenzene 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: yes IMDG Marine pollutant: yes IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use REACH - Candidate List of Substances of Very High Concern for Authorisation (Article 59). : nitrobenzene-d5 REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : nitrobenzene-d5



15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!