Products

Methyl methacrylate-d8, polymerized

99 atom%D

Item number1126-1X1G
FormulaC5D8O2
Molecular weight108,17 g/mol
Quantity 1x1g

Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 30.05.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Methyl methacrylate-d8, polymerized
Catalog No.:1126-1X1G
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Permoserstrasse 15

04318 Leipzig
Germany

Tel. +49 341 5295 183
Fax. +49 341 5295 182
E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Skin sensitization (Category 1), H317 Specific target organ toxicity - single exposure (Category 2), H371 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Label elements
Pictogramflamme
flamme
GHS07 exclam
exclam
GHS08 silhouete
silhouete
2.2 Label elements Labelling according Regulation (EC) No 1272/2008
Signal word Danger
Hazard statement(s) H225 Highly flammable liquid and vapor. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H371 May cause damage to organs.
Precautionary statement(s) P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P260 Do not breathe dust/ fume/ gas/ mist/ vapors/ spray. P280 Wear protective gloves. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard Statements none 2.3 Other hazards - none
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances Synonyms : Methyl-d3 methacrylate-d5

Formula : C5D8O2 Molecular weight : 108,09 g/mol CAS-No. : 35233-69-3

Component: methyl methacrylate-d8
Classification: Flam. Liq. 2; Skin Irrit. 2; Eye Irrit. 2; Skin Sens. 1; STOT SE 2; STOT SE 3; H225, H315, H319, H317, H371, H335
Concentration: <= 100 %
FormulaC5D8O2
Molecular Weight (g/mol)108.17
CAS-No.
FIRST AID MEASURES4.1 Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers.
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters Ingredients with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment

Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.
Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Color: colorless b) Odor No data available c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -48 °C - lit. f) Initial boiling point and boiling range 100 °C - lit. g) Flash point 9 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 12,5 %(V) Lower explosion limit: 2,12 %(V) k) Vapor pressure No data available l) Vapor density No data available m) Relative density 1,011 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: n-octanol/water No data available p) Autoignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY10.1 Reactivity No data available 10.2 Chemical stability Polymerizes with evolution of heat. Avoid contact with incompatible materials. Unless inhibited, product can polymerize, raising temperature and pressure, possibly rupturing container. Check inhibitor content often adding to bulk liquid if needed. Do not blanket or mix with oxygen-free gas as it renders inhibitor ineffective. Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions Polymerizes readily unless inhibited. 10.4 Conditions to avoid Heat, flames and sparks. Extremes of temperature and direct sunlight. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - 7.872 mg/kg Remarks: Behavioral:Coma. Behavioral:Muscle weakness. Respiratory disorder LC50 Inhalation - Rat - 4 h - 78.000 mg/l LD50 Dermal - Rabbit - > 5.000 mg/kg Remarks: Prolonged skin contact may cause skin irritation and/or dermatitis. Skin corrosion/irritation No data available Serious eye damage/eye irritation No data available Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure No data available Aspiration hazard No data available Additional Information RTECS: Not available
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 125,5 - 275,0 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 720 mg/l - 48 h
Toxicity to algae LC50 - Pseudokirchneriella subcapitata (green algae) - 170 mg/l - 96 h 12.2 Persistence and degradability No data available 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment PBT/vPvB assessment not available as chemical safety assessment not required/not conducted 12.6 Other adverse effects No data available
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product.
TRANSPORT INFORMATION14.1 UN number ADR/RID: 1247 IMDG: 1247 IATA: 1247 14.2 UN proper shipping name ADR/RID: METHYL METHACRYLATE MONOMER, STABILIZED IMDG: METHYL METHACRYLATE MONOMER, STABILIZED IATA: Methyl methacrylate monomer, stabilized 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II
14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.



15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!