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Trifluoroacetic acid-d

99.5 atom%D

Item number1174-10X0.75ML
CAS599-00-8
FormulaC2DF3O2
Molecular weight115,03 g/mol
Quantity 10x0.75ml
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Trifluoroacetic acid-d

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Safety Data Sheetaccording to Regulation (EC) No 1907/2006 (REACH)
Classifications according to Regulation (EC) No 1272/2008.
Printdate 30.05.2024
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product name:Trifluoroacetic acid-d
Catalog No.:1174-10X0.75ML
Relevant identified uses of the substance or mixtureIdentified: Laboratory chemical
uses: R&D
Uses advised against:HPC Standards GmbH
Permoserstrasse 15

04318 Leipzig
Germany

Tel. +49 341 5295 183
Fax. +49 341 5295 182
E-mail: info@armar-europa.de
HAZARDS IDENTIFICATION2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Inhalation (Category 4), H332 Skin corrosion (Sub-category 1A), H314 Serious eye damage (Category 1), H318 Long-term (chronic) aquatic hazard (Category 3), H412
Label elements
PictogramGHS05 acid
acid
GHS07 exclam
exclam
2.2 Label elements Labelling according Regulation (EC) No 1272/2008

Signal word Danger
Hazard statement(s) H314 Causes severe skin burns and eye damage. H332 Harmful if inhaled. H412 Harmful to aquatic life with long lasting effects.
Precautionary statement(s) P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor.
Supplemental Hazard Statements none 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
COMPOSITION/INFORMATION ON INGREDIENTS3.1 Substances Formula : C2DF3O2 Molecular weight : 115,02 g/mol CAS-No. : 599-00-8 EC-No. : 209-961-2

Component: Trifluoroacetic [2H]acid
Classification: Acute Tox. 4; Skin Corr. 1A; Eye Dam. 1; Aquatic Chronic 3; H332, H314, H318, H412
Concentration: <= 100 %
FormulaC2DF3O2
Molecular Weight (g/mol)115.03
CAS-No.599-00-8
FIRST AID MEASURES4.1 Description of first aid measures General advice Consult a physician. Show this safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available
FIRE-FIGHTING MEASURES5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen fluoride 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information No data available
ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal. 6.4 Reference to other sections For disposal see section 13.
HANDLING AND STORAGE7.1 Precautions for safe handling Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. Store under inert gas. hygroscopic 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment

Eye/face protection Tightly fitting safety goggles. Faceshield (8-inch minimum). Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.
The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.
Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.
PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical properties a) Appearance Form: liquid b) Odour No data available c) Odour Threshold No data available d) pH No data available e) Melting point/freezing point No data available f) Initial boiling point and boiling range 75 °C - lit. g) Flash point No data available h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapour pressure No data available l) Vapour density No data available m) Relative density 1,493 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: n-octanol/water No data available p) Auto-ignition temperature No data available q) Decomposition temperature
No data available
r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information No data available
STABILITY AND REACTIVITY10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Avoid moisture. 10.5 Incompatible materials No data available 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen fluoride Other decomposition products - No data available In the event of fire: see section 5
TOXICOLOGICAL INFORMATION11.1 Information on toxicological effects Acute toxicity LC50 Inhalation - Rat - 4 h - 10 mg/l Remarks: (External MSDS) Skin corrosion/irritation Necrosis Causes poorly healing wounds. Serious eye damage/eye irritation Eyes - Rabbit Result: Causes burns. Remarks: (External MSDS) Causes serious eye damage. Respiratory or skin sensitisation Germ cell mutagenicity Ames test Salmonella typhimurium Result: negative (Lit.) Carcinogenicity IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity - single exposure Specific target organ toxicity - repeated exposure Aspiration hazard Additional Information RTECS: Not available


Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea
ECOLOGICAL INFORMATION12.1 Toxicity
Toxicity to fish LC50 - Danio rerio (zebra fish) - > 1.200 mg/l - 96 h Remarks: (Lit.)
Toxicity to daphnia and other aquatic invertebrates EC50 - Daphnia magna (Water flea) - 1.200 mg/l - 48 h Remarks: (Lit.)
Toxicity to algae IC50 - Chlorella vulgaris (Fresh water algae) - > 1.200 mg/l - 72 h Remarks: (Lit.) 12.2 Persistence and degradability Biodegradability Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301D) 12.3 Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life with long lasting effects.
DISPOSAL CONSIDERATIONS13.1 Waste treatment methods Product Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
TRANSPORT INFORMATION14.1 UN number ADR/RID: 2699 IMDG: 2699 IATA: 2699 14.2 UN proper shipping name ADR/RID: TRIFLUOROACETIC ACID IMDG: TRIFLUOROACETIC ACID IATA: Trifluoroacetic acid 14.3 Transport hazard class(es) ADR/RID: 8 IMDG: 8 IATA: 8 14.4 Packaging group ADR/RID: I IMDG: I IATA: I 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available
REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006. REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) :



15.2 Chemical safety assessment For this product a chemical safety assessment was not carried out
OTHER INFORMATIONThe above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. For lab use only!