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Benzene-d6
100 atom%D
| Item number | 1042-1X10ML |
| CAS | 1076-43-3 |
| Formula | C6D6 |
| Molecular weight | 84,15 g/mol |
| Quantity | 1X10ML |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
99 atom%D |  | 1002-10X0.75ML | 10X1ML | Please log in. |
99 atom%D |  | 1002-1X100ML | 1X100ML | Please log in. |
99 atom%D |  | 1002-1X10ML | 1X10ML | Please log in. |
99 atom%D |  | 1002-1X25ML | 1X25ML | Please log in. |
99 atom%D |  | 1002-1X50ML | 1X50ML | Please log in. |
99.5 atom%D |  | 1040-10X0.75ML | 10X1ML | Please log in. |
99.5 atom%D |  | 1040-1X100ML | 1X100ML | Please log in. |
99.5 atom%D |  | 1040-1X10ML | 1X10ML | Please log in. |
99.5 atom%D |  | 1040-1X25ML | 1X25ML | Please log in. |
99.5 atom%D |  | 1040-1X50ML | 1X50ML | Please log in. |
99.8 atom%D |  | 1041-10X0.75ML | 10X1ML | Please log in. |
100 atom%D |  | 1042-10X0.75ML | 10X1ML | Please log in. |
100 atom%D |  | 1042-1X10ML | 1X10ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 15.10.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Benzene-d6 |
| Catalog No.: | 1042-1X10ML |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Permoserstrasse 15 04318 Leipzig Germany Tel. +49 341 5295 183 Fax. +49 341 5295 182 E-mail: info@armar-europa.de |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Flammable liquids (Category 2), H225 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Germ cell mutagenicity (Category 1B), H340 Carcinogenicity (Category 1A), H350 Specific target organ toxicity - repeated exposure (Category 1), H372 Aspiration hazard (Category 1), H304 Long-term (chronic) aquatic hazard (Category 3), H412 |
| Label elements | |
| Pictogram | flamme flamme GHS07 exclam exclam GHS08 silhouete silhouete |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H225 Highly flammable liquid and vapor. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H340 May cause genetic defects. H350 May cause cancer. H372 Causes damage to organs through prolonged or repeated exposure. H412 Harmful to aquatic life with long lasting effects. Precautionary statement(s) P201 Obtain special instructions before use. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P301 + P310 + P331 IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. P302 + P352 IF ON SKIN: Wash with plenty of water. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none Restricted to professional users. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : Hexadeuterobenzene Formula : C6D6 Molecular weight : 84,15 g/mol CAS-No. : 1076-43-3 EC-No. : 214-061-8 Component Classification Concentration (2H6)benzene Flam. Liq. 2; Skin Irrit. 2; Eye Irrit. 2; Muta. 1B; Carc. 1A; STOT RE 1; Asp. Tox. 1; Aquatic Chronic 3; <= 100 % H225, H315, H319, H340, H350, H372, H304, H412 |
| Formula | C6D6 |
| Molecular Weight (g/mol) | 84.15 |
| CAS-No. | 1076-43-3 |
| FIRST AID MEASURES | 4.1 Description of first-aid measures General advice Consult a physician. Show this material safety data sheet to the doctor in attendance. If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Carbon oxides 5.3 Advice for firefighters Wear self-contained breathing apparatus for firefighting if necessary. 5.4 Further information Use water spray to cool unopened containers. |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. For personal protection see section 8. 6.2 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. 6.3 Methods and materials for containment and cleaning up Contain spillage, and then collect with an electrically protected vacuum cleaner or by wetbrushing and place in container for disposal according to local regulations (see section 13). 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Avoid exposure - obtain special instructions before use.Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Handle and store under inert gas. Hygroscopic. 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters 8.2 Exposure controls Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Personal protective equipment Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the CE approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario. Body Protection Complete suit protecting against chemicals, Flame retardant antistatic protective clothing., The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid Color: colorless b) Odor No data available c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: 6,8 °C - lit. f) Initial boiling point and boiling range 79,1 °C at 1.013 hPa - lit g) Flash point -11 °C - closed cup h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits Upper explosion limit: 8 %(V) Lower explosion limit: 1,3 %(V) k) Vapor pressure 221 hPa at 37,7 °C 99,5 hPa at 20 °C l) Vapor density 2,91 - (Air = 1.0) m) Relative density 0,95 g/cm3 at 25 °C n) Water solubility No data available o) Partition coefficient: n-octanol/water log Pow: 2,13 at 25 °C p) Autoignition temperature No data available q) Decomposition temperature No data available r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Relative vapor density 2,91 - (Air = 1.0) |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability Stable under recommended storage conditions. 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid Heat, flames and sparks. 10.5 Incompatible materials Acids, Bases, Halogens, Strong oxidizing agents, metal salts 10.6 Hazardous decomposition products Hazardous decomposition products formed under fire conditions. - Carbon oxides Other decomposition products - No data available In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male - > 2.000 mg/kg (OECD Test Guideline 401) LC50 Inhalation - Rat - female - 4 h - 43,7 mg/l (OECD Test Guideline 403) Skin corrosion/irritation Skin - Rabbit Result: Irritating to skin. - 4 h (OECD Test Guideline 404) Serious eye damage/eye irritation Eyes - Rabbit Result: Eye irritation Remarks: (ECHA) Respiratory or skin sensitization Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) Germ cell mutagenicity May cause genetic defects. Ames test Salmonella typhimurium Result: negative Mutagenicity (mammal cell test): chromosome aberration. Chinese hamster lung cells Result: positive In vitro mammalian cell gene mutation test Result: positive OECD Test Guideline 474 Mouse - male - Bone marrow Result: positive Carcinogenicity May cause cancer. Positive evidence from human epidemiological studies. IARC: No ingredient of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity No data available Specific target organ toxicity - single exposure No data available Specific target organ toxicity - repeated exposure Causes damage to organs through prolonged or repeated exposure. - Blood Aspiration hazard May be fatal if swallowed and enters airways Additional Information Repeated dose toxicity - Rat - male and female - Oral - 120 d - NOAEL (No observed adverse effect level) - 100 mg/kg - LOAEL (Lowest observed adverse effect level) - 25 mg/kg Subchronic toxicity RTECS: Not available Nausea, Dizziness, Headache, Inhalation of high concentrations of benzene may have an initial stimulatory effect on the central nervous system characterized by exhilaration, nervous excitation and/or giddiness, depression, drowsiness, or fatigue. The victim may experience tightness in the chest, breathlessness, and loss of consciousness. Tremors, convulsions, and death due to respiratory paralysis or circulatory collapse can occur in a few minutes to several hours following severe exposures. Aspiration of small amounts of liquid immediately causes pulmonary edema and hemorrhage of pulmonary tissue. Direct skin contact may cause erythema. Repeated or prolonged skin contact may result in drying, scaling dermatitis, or development of secondary skin infections. The chief target organ is the hematopoietic system. Bleeding from the nose, gums, or mucous membranes and the development of purpuric spots, pancytopenia, leukopenia, thrombocytopenia, aplastic anemia, and leukemia may occur as the condition progresses. The bone marrow may appear normal, aplastic or hyperplastic, and may not correlate with peripheral bloodforming tissues. The onset of effects of prolonged benzene exposure may be delayed for many months or years after the actual exposure has ceased., To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Systemic effects: After absorption: agitation, Headache, Dizziness, inebriation, Tiredness, CNS disorders, narcosis, respiratory arrest Subacute toxicity After a latency period: Changes in the blood count, haemolysis Other dangerous properties can not be excluded. This substance should be handled with particular care. Blood - Irregularities - Based on Human Evidence |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to fish flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 5,3 mg/l - 96 h (OECD Test Guideline 203) Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 100 mg/l - 72 h (OECD Test Guideline 201) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 28 d Result: 96 % - Readily biodegradable. (OECD Test Guideline 301F) 12.3 Bioaccumulative potential Bioaccumulation Leuciscus idus (Golden orfe) - 3 d - 0,05 mg/l((2H6)benzene) Bioconcentration factor (BCF): 10 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects Harmful to aquatic life with long lasting effects. Endangers drinking-water supplies if allowed to enter soil or water. Discharge into the environment must be avoided. |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product Burn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposal company. Contaminated packaging Dispose of as unused product. |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1114 IMDG: 1114 IATA: 1114 14.2 UN proper shipping name ADR/RID: BENZENE, SOLUTION IMDG: BENZENE, SOLUTION IATA: Benzene, SOLUTION 14.3 Transport hazard class(es) ADR/RID: 3 IMDG: 3 IATA: 3 14.4 Packaging group ADR/RID: II IMDG: II IATA: II 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : (2H6)benzene 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |