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Chloroform-d stab. with Ag
100 atom%D
| Item number | 1055-1X100ML |
| CAS | 865-49-6 |
| Formula | CCl3D |
| Molecular weight | 120,38 g/mol |
| Quantity | 1X100ML |
| CoA / MSDS | Retrieve CoA Retrieve MSDS |
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Part of Product groups:
Product Variations:
Product | Catalog No./ CAS No. | Quantity | Price | |
|---|---|---|---|---|
99.8 atom%D |  | 1054-10X0.75ML | 10X1ML | Please log in. |
100 atom%D |  | 1055-10X0.75ML | 10X1ML | Please log in. |
99.8 atom%D |  | 1054-1X100ML | 1X100ML | Please log in. |
99.8 atom%D |  | 1054-1X25ML | 1X25ML | Please log in. |
99.8 atom%D |  | 1054-1X500ML | 1X500ML | Please log in. |
100 atom%D |  | 1055-1X100ML | 1X100ML | Please log in. |
| Safety Data Sheet | according to Regulation (EC) No 1907/2006 (REACH) Classifications according to Regulation (EC) No 1272/2008. Printdate 15.10.2024 |
| IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING | |
| Product name: | Chloroform-d stab. with Ag |
| Catalog No.: | 1055-1X100ML |
| Relevant identified uses of the substance or mixture | Identified: Laboratory chemical uses: R&D |
| Uses advised against: | HPC Standards GmbH Permoserstrasse 15 04318 Leipzig Germany Tel. +49 341 5295 183 Fax. +49 341 5295 182 E-mail: info@armar-europa.de |
| HAZARDS IDENTIFICATION | 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 3), H331 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Carcinogenicity (Category 2), H351 Reproductive toxicity (Category 2), H361d Specific target organ toxicity - single exposure (Category 3), Central nervous system, H336 Specific target organ toxicity - repeated exposure, Oral (Category 1), Liver, Kidney, H372 |
| Label elements | |
| Pictogram | GHS06 skull skull GHS08 silhouete silhouete |
| 2.2 Label elements Labelling according Regulation (EC) No 1272/2008 Pictogram Signal word Danger Hazard statement(s) H302 Harmful if swallowed. H315 Causes skin irritation. H319 Causes serious eye irritation. H331 Toxic if inhaled. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. H361d Suspected of damaging the unborn child. H372 Causes damage to organs (Liver, Kidney) through prolonged or repeated exposure if swallowed. Precautionary statement(s) P201 Obtain special instructions before use. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P311 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. Supplemental Hazard Statements none For use in industrial installations only. 2.3 Other hazards This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher | |
| COMPOSITION/INFORMATION ON INGREDIENTS | 3.1 Substances Synonyms : Deuterochloroform Formula : CCl3D Molecular weight : 120,38 g/mol CAS-No. : 865-49-6 EC-No. : 212-742-4 Component Classification Concentration Chloroform-D1-Deuteration Acute Tox. 4; Acute Tox. 3; Skin Irrit. 2; Eye Irrit. <= 100 % 2; Carc. 2; Repr. 2; STOT SE 3; STOT RE 1; H302, H331, H315, H319, H351, H361d, H336, H372 Concentration limits: 20 %: STOT SE 3, H336; |
| Formula | CCl3D |
| Molecular Weight (g/mol) | 120.38 |
| CAS-No. | 865-49-6 |
| FIRST AID MEASURES | 4.1 Description of first-aid measures General advice First aider needs to protect himself. Show this material safety data sheet to the doctor in attendance. If inhaled After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen. In case of skin contact In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. In case of eye contact After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. If swallowed After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available |
| FIRE-FIGHTING MEASURES | 5.1 Extinguishing media Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing agents are given. 5.2 Special hazards arising from the substance or mixture Carbon oxides, Hydrogen chloride gas Not combustible. Ambient fire may liberate hazardous vapours 5.3 Advice for firefighters Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. 5.4 Further information Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system |
| ACCIDENTAL RELEASE MEASURES | 6.1 Personal precautions, protective equipment and emergency procedures Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. 6.2 Environmental precautions Do not let product enter drains. 6.3 Methods and materials for containment and cleaning up Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up carefully with liquid-absorbent material (e.g. Chemizorb®). Dispose of properly. Clean up affected area. 6.4 Reference to other sections For disposal see section 13. |
| HANDLING AND STORAGE | 7.1 Precautions for safe handling Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. For precautions see section 2.2. 7.2 Conditions for safe storage, including any incompatibilities Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Store under inert gas. Light sensitive. hygroscopic 7.3 Specific end use(s) Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| EXPOSURE CONTROLS/PERSONAL PROTECTION | 8.1 Control parameters Components with workplace control parameters Component CAS-No. Value Control parameters Basis Chloroform-d 865-49-6 TWA 2 ppm 10 mg/m3 Europe. Commission Directive 2000/39/EC establishing a first list of indicative occupational exposure limit values Remarks Identifies the possibility of significant uptake through the skin Indicative TWA 2 ppm 9.9 mg/m3 UK. EH40 WEL - Workplace Exposure Limits Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. Where no specific short-term exposure limit is listed, a figure three times the long-term exposure should be used 8.2 Exposure controls Appropriate engineering controls Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Eye/face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching gloves outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it. Body Protection Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Respiratory protection Where risk assessment shows air-purifying respirators are appropriate use a fullface respirator with multi-purpose combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Control of environmental exposure Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. |
| PHYSICAL AND CHEMICAL PROPERTIES | 9.1 Information on basic physical and chemical properties a) Appearance Form: liquid, clear Color: colorless b) Odor characteristic c) Odor Threshold No data available d) pH No data available e) Melting point/freezing point Melting point/range: -64 °C - lit. f) Initial boiling point and boiling range 60,9 °C - lit. g) Flash point > 60 °C at ca.1.019,2 hPa - closed cup - Regulation (EC) No. 440/2008, Annex, A.9 h) Evaporation rate No data available i) Flammability (solid, gas) No data available j) Upper/lower flammability or explosive limits No data available k) Vapor pressure ca.265,31 hPa at ca.25 °C l) Vapor density 4,12 - (Air = 1.0) m) Relative density 1,500 g/cm3 at 25 °C n) Water solubility 4,6 g/l at 20 °C - Regulation (EC) No. 440/2008, Annex, A.6 o) Partition coefficient: n-octanol/water log Pow: 1,5 at 20 °C - Bioaccumulation is not expected. p) Autoignition temperature No data available q) Decomposition temperature Distillable in an undecomposed state at normal pressure. r) Viscosity No data available s) Explosive properties No data available t) Oxidizing properties No data available 9.2 Other safety information Surface tension 72,3 mN/m at 0,99g/l at 20 °C - Surface tension Relative vapor density 4,12 - (Air = 1.0) |
| STABILITY AND REACTIVITY | 10.1 Reactivity No data available 10.2 Chemical stability The product is chemically stable under standard ambient conditions (room temperature) . 10.3 Possibility of hazardous reactions No data available 10.4 Conditions to avoid no information available 10.5 Incompatible materials Bases, Aluminum, Strong oxidizing agents, Magnesium, Sodium/sodium oxides, Lithium 10.6 Hazardous decomposition products Other decomposition products - No data available Hazardous decomposition products formed under fire conditions. - Carbon oxides, Hydrogen chloride gas In the event of fire: see section 5 |
| TOXICOLOGICAL INFORMATION | 11.1 Information on toxicological effects Acute toxicity LD50 Oral - Rat - male - 908 mg/kg (OECD Test Guideline 401) Skin corrosion/irritation Skin - Rabbit Result: Irritating to skin. - 24 h Remarks: (ECHA) Drying-out effect resulting in rough and chapped skin. Serious eye damage/eye irritation Eyes - Rabbit Result: Irritating to eyes. Remarks: (ECHA) Respiratory or skin sensitization Maximization Test - Guinea pig Result: negative (Regulation (EC) No. 440/2008, Annex, B.6) Germ cell mutagenicity Ames test Salmonella typhimurium Result: negative (ECHA) In vitro mammalian cell gene mutation test mouse lymphoma cells Result: positive (ECHA) Rat - male - Bone marrow Result: positive (ECHA) Carcinogenicity Suspected of causing cancer. IARC: 2B - Group 2B: Possibly carcinogenic to humans (Chloroform-D1-Deuteration) Reproductive toxicity Suspected of damaging the unborn child. Specific target organ toxicity - single exposure May cause drowsiness or dizziness. (in analogy to similar products) Specific target organ toxicity - repeated exposure Oral - Causes damage to organs through prolonged or repeated exposure. - Liver, Kidney Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Aspiration hazard No data available Additional Information RTECS: Not available Vomiting, Gastrointestinal disturbance, Cough, irritant effects, Shortness of breath To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. |
| ECOLOGICAL INFORMATION | 12.1 Toxicity Toxicity to daphnia and other aquatic invertebrates static test EC50 - Daphnia magna (Water flea) - 79 mg/l - 48 h Remarks: (ECHA) Toxicity to algae static test ErC50 - Chlamydomonas reinhardtii (green algae) - 13,3 mg/l - 72 h Remarks: (ECHA) Toxicity to bacteria static test EC50 - activated sludge - 0,48 mg/l - 24 h Remarks: (ECHA) 12.2 Persistence and degradability Biodegradability aerobic - Exposure time 14 d Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301C) Theoretical oxygen demand 1.346 mg/g 12.3 Bioaccumulative potential No data available 12.4 Mobility in soil No data available 12.5 Results of PBT and vPvB assessment This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. 12.6 Other adverse effects No data available |
| DISPOSAL CONSIDERATIONS | 13.1 Waste treatment methods Product See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions |
| TRANSPORT INFORMATION | 14.1 UN number ADR/RID: 1888 IMDG: 1888 IATA: 1888 14.2 UN proper shipping name ADR/RID: CHLOROFORM IMDG: CHLOROFORM IATA: Chloroform 14.3 Transport hazard class(es) ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1 14.4 Packaging group ADR/RID: III IMDG: III IATA: III 14.5 Environmental hazards ADR/RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user No data available |
| REGULATORY INFORMATION | 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. Authorisations and/or restrictions on use REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII) : Chloroform-D1-Deuteration Other regulations Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. 15.2 Chemical Safety Assessment For this product a chemical safety assessment was not carried out |
| OTHER INFORMATION | The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the product. For lab use only! |